Quaternized Poly(4-Vinylpyridine) Coated Activated Carbon: Diffusion Controlled Sorption of Chromium(VI)

Abstract

Quaternized poly(4-vinylpyridine) coated activated carbon has been proven to be successful in removal and recovery of Cr(VI) from aqueous solution. However, the key component of the mass transfer operations and the diffusion coefficient has not been determined. In this study, adsorption of Cr(VI) was investigated at different initial concentrations. A finite bath diffusion control model with changing bulk concentrations was derived analytically, and a constant related to radius of the absorbent particle and the fractional attainment of adsorption was first introduced into this model. Results indicated that the adsorbent provided fast adsorption kinetics and the modified diffusion-control model fitted the experimental data well. The observed sorption kinetics was consistent with the finite bath diffusion, with an average value of 4.10× 10−6 cm2 ∕s for the product of the distribution coefficient and the effective diffusivity in the adsorption of Cr(VI) on the quaternized poly(4-vinylpyridine) coated activat...