Abstract
(Liquid + liquid) equilibrium tie-lines were measured for one ternary system { x 1H 2O + x 2(CH 3) 2CHOH + (1 − x 1 − x 2)CH 3C(CH 3) 2OCH 3} and one quaternary system { x 1H 2O + x 2(CH 3) 2CHOH + x 3CH 3C(CH 3) 2OCH 3 + (1 − x 1 − x 2 − x 3)(CH 3) 2CHOCH(CH 3) 2} at T = 298.15 K and P ∘ = 101.3 kPa. The experimental (liquid + liquid) equilibrium results were satisfactorily correlated by modified and extended UNIQUAC models both with ternary and quaternary parameters in addition to binary ones.
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