Abstract

Pyridazino[1,6-a]benzimidazolium cations and 1-(o-methylaminoaryl)-4-acetylpyrazoles are formed simultaneously in approximately equal amounts in the reaction of excess acetylacetone with quaternary 1-aminobenzimidazolium salts in aqueous potassium carbonate solution. Mesoionic pyridazinobenzimidazoles and the corresponding 4-ethoxycarbonylpyrazoles were obtained with acetoacetic ester under similar conditions.

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