Abstract

The GW approximation and the Bethe‐Salpeter equation (BSE) have been used to calculate quasiparticle and optical excitations in solid Ne and Ar. Absolute positions of quasiparticle and quasihole energies are found to be in very good agreement with experimental values. Binding energies of Frenkel excitons for these systems calculated using the BSE are also in good agreement with experiment. Splitting of excitons into longitudinal and transverse modes is calculated and found to be approximately twice the experimentally measured value.

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