Quasi-diffusion controlled high rate sodium-ion storage performance of flame pyrolysis derived spherical hard carbon

Abstract

Hard carbon (HC) is identified as a potential anode for sodium ion batteries (SIBs) due to its outstanding electrochemical performance. However, selection of synthesis routes and its precursors remain crucial to develop the HC of desired microstructures for enhanced sodium-ion storage. Herein, we employed novel flame pyrolysis route to prepare spherical HC nanoparticles (<100 nm) from a liquid precursor derived from a low-cost bio-source. The as prepared carbon has been subjected to different calcination temperatures to optimize the porosity and surface area in order to achieve maximum sodium ion storage. The HC calcined at 1200 °C has shown the optimum electrochemical performance with a high reversible capacity of ∼287 mAh/g at 0.1C (1C = 300 mA/g). It shows 72 % of capacity retention after 490 cycles when cycled at 1C, with initial reversible specific capacity of ∼235 mAh/g. Excellent rate performance has been seen even at 20 C (6 A/g) with high specific capacity of 118 mAh/g at 70 % capacity retention after 2000 cycles, which is one of the highest values reported so far. Structural and morphological characterization of HC prepared at different temperatures are carried out using X-ray powder diffraction (XRD), small angle X-ray scattering (SAXS), Raman spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques. Particle size and morphology altogether have played significant role in achieving high specific capacity and C-rate performance by providing shorter diffusion path and larger sodium ion storage sites.