Abstract

Sulfur dioxide (SO2) trace gas detection based on quartz-enhanced photoacoustic spectroscopy (QEPAS) using a continuous wave, distributed feedback quantum cascade laser operating at 7.24 μm was performed. Influence of water vapor addition on monitored QEPAS SO2 signal was also investigated. A normalized noise equivalent absorption coefficient of NNEA (1σ) = 1.21 × 10−8 cm−1 W Hz−1/2 was obtained for the ν3 SO2 line centered at 1,380.93 cm−1 when the gas sample was moisturized with 2.3 % H2O. This corresponds to a minimum detection limit (1σ) of 63 parts per billion by volume for a 1 s lock-in time constant.

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