Abstract

We derive the kinetic equations for the coupled single-particle density matrix $\ensuremath{\rho}$ and the electromagnetic density matrix $R$ to lowest order in the dimensionless coupling constant ${\ensuremath{\beta}}^{2}\ensuremath{\equiv}{(\frac{{\ensuremath{\omega}}_{L}}{{\ensuremath{\omega}}_{D}})}^{2}$. The laser frequency ${\ensuremath{\omega}}_{L}$ is ${(4\ensuremath{\pi})}^{\ensuremath{-}\frac{1}{2}}{(\mathfrak{N}{r}_{0}{\ensuremath{\lambda}}^{2})}^{\frac{1}{2}}{\ensuremath{\omega}}_{0}$ where $\mathfrak{N}$ is the number of two-level systems per unit volume, ${r}_{0}$ is the classical electron radius, $\ensuremath{\lambda}$ is the wavelength of the radiation, and $k{\ensuremath{\omega}}_{0}$ is the two-level energy difference. The Doppler frequency ${\ensuremath{\omega}}_{D}$ characterizes the center-of-mass motion. For gas lasers ${\ensuremath{\beta}}^{2}$ is much less than 1 and, consequently, we generalize and use the Bogoliubov derivation of kinetic equations for weak interactions. We find solutions when the average field vanishes and which include spontaneous emission correctly. The single-particle density matrix and the radiation density matrix are coupled through their second moments. When we substitute the solution of the second-moment equations into the density-matrix equations, we find that each density matrix satisfies an uncoupled linear equation with known time-dependent coefficients. We introduce and discuss dissipation from the density-matrix point of view. With the use of the density-matrix formalism we indicate that the correct expansion parameter for higher order kinetic equations is ${\ensuremath{\beta}}^{2}$.

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