Abstract
We suggest a statistical model for the process of multiphoton unimolecular dissociation which considers the energy levels of the vibrational active mode, a quasi-continuous heat bath constituted by the energy levels of the remaining modes of the molecule and an electronically excited fragment resulting from the dissociation. The master equation for the system and expressions for the moments are derived and discussed in the standard second-quantization formalism. From the master equation the diagonal and off-diagonal density matrix elements are evaluated and some discussion on their applications to establish the change of light statistics is given.
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