Quantum electrodynamic corrections for valence electrons in Eka-Hg

Abstract

The quantum electrodynamic (QED) corrections to the coupling energy of valence electrons in heavy and superheavy nuclei are calculated in the effective local-potential approximation, as well as by the Hartree-Fock-Dirac self-consistent method. It is clearly shown that the contribution from the QED corrections is within the accuracy of modern calculations, which do not take into account QED effects. It is shown that, in certain cases, to exactly calculate the coupling energy of electrons in heavy and superheavy atoms, it is necessary to take into account the self-consistency, which shows that the inaccuracy of the use of the method of the effective local potential in calculations of QED effects can exceed 10%, which is also within the limits of calculations of the coupling energy without taking into account QED effects.