Abstract
A multiconfiguration version of the time-dependent Hartree approximation has been applied to various molecular systems, including direct photodissociation, vibrational predissociation and photodissociation on a solid surface. It is shown that the omission of dynamic correlations by the simple time-dependent Hartree approximation can be corrected by the multiconfiguration formalism and the results converge to the exact solution. Because of a different scaling law with the dimensionality of the problem, this method may find applications in large dimensional systems which are not accessible by conventional exact methods.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
