Quantum decoherence and quasi-equilibrium in open quantum systems with few degrees of freedom: Application to 1H NMR of nematic liquid crystals

Abstract

Explanation of decoherence and quasi-equilibrium in systems with few degrees of freedom demands a deep theoretical analysis that considers the observed system as an open quantum system. In this work, we study the problem of decoherence of an observed system of quantum interacting particles, coupled to a quantum lattice. Our strategy is based on treating the environment and the system-environment Hamiltonians fully quantum mechanically, which yields a representation of the time evolution operator useful for disentangling the different time scales underlying in the observed system dynamics. To describe the possible different stages of the dynamics of the observed system, we introduce quantum mechanical definitions of essentially isolated, essentially adiabatic, and thermal-contact system-environment interactions. This general approach is then applied to the study of decoherence and quasi-equilibrium in proton nuclear magnetic resonance ((1)H NMR) of nematic liquid crystals. A summary of the original results of this work is as follows. We calculate the decoherence function and apply it to describe the evolution of a coherent spin state, induced by the coupling with the molecular environment, in absence of spin-lattice relaxation. By assuming quantum energy conserving or non-demolition interactions, we identify an intermediate time scale, between those controlled by self-interactions and thermalization, where coherence decays irreversibly. This treatment is also adequate for explaining the buildup of quasi-equilibrium of the proton spin system, via the process we called eigen-selectivity. By analyzing a hypothetical time reversal experiment, we identify two sources of coherence loss which are of a very different nature and give rise to distinct time scales of the spin dynamics: (a) reversible or adiabatic quantum decoherence and (b) irreversible or essentially adiabatic quantum decoherence. Local irreversibility arises as a consequence of the uncertainty introduced by the coupling with an infinite quantum environment. The reversible part can be represented by a semiclassical model, similar to standard line-shape adiabatic models. By exploiting the separation existing between the time scales of the spin coherences and the irreversible decoherence, we present a novel technique to obtain the orientational molecular distribution function for a nematic liquid crystal. The procedure is based on the comparison of the observed coherence time evolution and numerical calculation under the adiabatic quantum decoherence approach. As an example, it is used the experimental free induction decay from a nematic PAA(d6) sample to extract such an orientational distribution. This is the first theoretical description of the experimental liquid crystal NMR signal in the time domain. On the contrary, the irreversible decoherence is intrinsically full-quantum mechanical, as it is governed by the commutation properties of the environment and the spin-lattice Hamiltonians. Consistently, it depends on the molecular correlation in a decisive way, since it vanishes under a mean-field model for the molecular dynamics. The results of this work can contribute to the understanding of the open question of the applicability of the spin-temperature concept in spin systems with few degrees of freedom.