Abstract
A potential surface of rotational transformations of 1,3-di(silylmethyl)imidazol-2-ylidene and its halo-substituted analogs has been analyzed using quantum-chemical methods. Coordination interactions of the carbene center with Si-fragments have been studied. It is shown that the above interaction results in a structural reorganization of the silicon centers from the tetrahedral state to the trigonal–bipyramidal. This leads to a considerable stabilization of compounds in the planar state. The stabilization effect is strengthened by halogenation.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.