Abstract
Abstract The geometry of trans-HN=NH, cis-HN=NH and N=NH2 containing no, one or two 15N labeled atoms was optimized. The corresponding infrared vibrations were evaluated using a linear scaling factor. For each of these compounds at least one vibration can be found, which enables to distinguish between heteroisotopic 14N=15N and homoisotopic 14N=14N or 15N=15N species. Independent of the 15N labeling, only trans-conformation should be found in the reaction mixture under equilibrium conditions.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
