Abstract

The thermodynamic properties and equilibrium constants of cyclotri-, tetra-, penta-and hexaphosphates systems with di-and trivalent cations, p-and d-elements for different cyclophosphate / metal molar ratios equal 2:1, 1:1, 1:2 and 1:3 were calculated by using PM3 quantum-chemical semi-empirical method. It was shown that the state of systems equilibrium determines their strength and formation patterns.

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