Abstract
Treatment of the Schiff base 2-((E)-(2-hydroxy propylimino)methyl)phenol with MoO2(acac)2 in dry methanol gave the mononuclear complex (methanol{6-[(2-oxidopropyl)iminometh-yl]phenolato}dioxidomolybdenum(VI), which was characterized by X-ray crystal analysis, and it has monoclinic space group p21/c, and a=10.330(17)Å, b=9.397(15)Å, c=13.695(2)Å, V=1252.1(3)Å3, and Z=4. B3LYP theoretical method with DZP basis sets calculations nicely reproduces the X-ray experimental geometry, molecular orbital levels and the other structural properties for this complex.
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