Abstract

Quantity‐intensity (Q‐I) relation studies were often used to supplement information obtained from conventional soil tests for the estimation of potassium (K) needs of crops. With a view to ascertaining the reliability of the Q‐I relation parameters for comprehensive characterization of K dynamics in typical Nigerian soils, K values derived from Q‐I isotherms were related to neutral normal ammonium acetate (1 N NH4OAc, pH 7.0) (exchangeable) K, other soil K forms [non‐exchangeable (Kne), exchange (Ke), mineral K (K m ), and solution K (Ks)] and the K uptake by Guinea‐corn (Sorghum bicolor, var. LS 187) subjected to weekly cuts in Neubauer cultivation vessels. Most of the soil K (about 98%) was in the form of soil minerals while less than 1% was plant available whereas about 1% was trapped within the interlattice layers of the clay minerals (as fixed K or Kne). Mineral K (Km) content was closely related to total K (Kt), but not to the other forms, Kne, Ke, and Ks. A close relationship was noted between the two components of labile K (Ke and Ks). Except for % K saturation, the relationships between the K measurements with plant response were poor. The results of these investigations clearly demonstrate that the Q‐I relation could not adequately characterize the K dynamics of these tropical soils.

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