Quantitative XPS analysis of amine-terminated dendritic functionalized halloysite nanotubes decorated on PAN nanofibrous membrane and adsorption/filtration of Cr(VI)

Abstract

Quantitative XPS analysis of the active functional groups on the surface of nanofiber membranes is an important issue for evaluating the potential efficiency of the membranes in removing heavy metals from aqueous solutions. This research is developing a novel composite nanofiber for accessibility adsorption groups on the surface of the electrospun membrane for effective removal of Cr(VI). For this purpose, three generations (G1, G2, and G3) of poly(amidoamine) dendrimers (PAMAM) were grafted onto the surface of halloysite nanotubes (HNTs). Functionalized HNTs (F-HNTs) were decorated on the surface of polyacrylonitrile (PAN) nanofiber layers in different ratios by simultaneous electrospinning and electrospraying techniques. The results showed that the decoration with F-HNTs made the surface of the membranes superhydrophilic. The removal efficiency of the optimal sample with 10 % third-generation F-HNTs (PAN/HNTs-G3-10 %) reached 96 % within 5 min. The mechanism for the removal of Cr(VI) ions in the PAN/HNTs-G3-10 % membrane was electrostatic interaction, chelation, and reduction. X-ray photoelectron spectrometer (XPS) analysis was used to characterize the quantitative and qualitative correlation dependencies between the removal of Cr(VI) and the amine functional groups of different generations decorated onto the electrospun layer. Quantitative analysis of the amine-terminated dendritic groups has revealed that the percentage of Cr(VI) removal is proportional to the number of terminal amine groups. Furthermore, PAN/HNTs-G2 and PAN/HNTs-G3 composite nanofiber membranes showed significantly lower leachability of nanoparticles and higher mechanical strength compared to other membranes due to the formation of ionic bonds between the amine-terminated dendritic of HNTs-G2 and HNTs-G3 and the cyanide groups of PAN. Effects of competing heavy metal ions on Cr(VI) adsorption follow the order of Zn(II) > Cu(II) > Ni(II).