Abstract
Controlled dispersion as generated in flow injection analysis permits essentially infinite known compositional variations. If carrier-sample compositions are appropriately chosen, reasonably accurate values of equilibrium constants are easily obtained in proton-ligand and metal-ligand systems with multidimensional spectral detection. Choice of an appropriate carrier-sample buffer system is critical in proton-ligand studies and is discussed in detail. Metal-ligand association constants are reliably obtained with both high and low conditional stability constants. 10 references, 4 figures.
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