Quantitative studies of NO emissions from various reaction pathways in swirling combustion of hydrogen-enriched methane

Abstract

Hydrogen-enriched methane is a promising alternative fuel for carbon dioxide reduction. Large eddy simulations of turbulent combustion and NO emission are carried out using a new numerical method, which incorporates an improved NO prediction model and a recently-developed NO reaction pathway separation approach. Quantitative analyses of NO formations from all reaction pathways are conducted in an open swirl burner (combustion in the open environment) with hydrogen-enriched methane at a constant thermal power of 10.85 kW at the atmospheric pressure. Results indicate that different NO reaction pathways response very differently with hydrogen addition. In the open burner with hydrogen enrichment up to 60 %, the prompt NO makes the largest (around 50 %) contribution to the total NO emission, but its relative contribution decreases with hydrogen addition. The thermal NO strongly increases with hydrogen addition, but it accounts for only around 25 % of the total NO emission in hydrogen-enriched cases, because of the reduced high-temperature zone by co-flow air dilution. NO formation from the NNH pathway largely increases and contributes around 20 % to the total NO emission with hydrogen enrichment. Results would provide quantitative understanding of NO emission in the bluff-body stabilized swirling combustion of hydrogen-enriched methane in an open burner.