Abstract
A thermodynamic equilibrium between the locally excited state and the twisted intramolecular charge-transfer (TICT) state in p-(dimethylamino)benzonitrile and ethyl p-(dimethylamino)benzoate is used to probe unusual solute-solvent interactions in supercritical trifluoromethane and carbon dioxide mixtures. Well-defined locally excited state fluorescence spectra of the two molecules are obtained through application of principal component analysis
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