Abstract

Aiming to determine the size distribution and surface area per unit mass of catalyst nanoparticles for fuel cells, we have developed a novel method of digital image processing that quantitatively determines the size of individual nanoparticles from atomic-resolution transmission electron microscopy images. After introducing the basic concept of this new method, we demonstrate its efficiency using platinum nanoparticles on carbon support as a model system. Special attention is given to the error that can be introduced by estimating the surface area per unit mass from the distribution of particle diameters in the presence of asymmetry of the particle size about the mean.

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