Quantitative analysis on the impact factors of salt weathering for sandstone grottoes along Silk Road, China

Abstract

A large number of exquisite sandstone grottoes remaining along the Silk Road in Northwest China suffer from severe salt damage due to the vulnerability of the sandstone materials used and long-term continuous fluctuation of environmental conditions. Exploring the mechanism of salt weathering is crucial for the conservation of these grottoes. This study aims to quantitatively analyze the damage potential and the main impact factors of salt weathering in 14 grottoes along the Silk Road that were selected and investigated by using visual evaluation, salt analysis including thermodynamic modeling, and a comprehensive evaluation based on the entropy weight method. The results indicate that salt weathering of the sandstone grottoes is primarily characterized by efflorescences, peeling, and powdering. The overall salt content within the weathering layer typically exceeds a threshold of 1 %. Within the semi-arid area, the humidity fluctuations critical for significant volume changes in crystalline salts fall within the ranges 46–76 % and 16–30 %. In the semi-humid area, these ranges are 58–90 %, 42–50 %, and 16–30 %. A total of 14 salts can precipitate in the study area with NaCl, NaNO3, KNO3, Na2SO4·xH2O and several double salts occuring most frequently. Generally, the damage degree of sandstones grottoes in the semi-humid area is more serious than that in the semi-arid area. Through a comparison of visual inspection and more comprehensive quantitative evaluation, it has been confirmed that the salt damage is primarily influenced by the factors salt content, salt type, and environmental conditions. Furthermore, the order of influence for each factor on salt weathering can be ranked as follows: salt content > salt type > environmental conditions. This study quantitatively reveals the impact of various factors on salt weathering and proposes a method to evaluate the salt damage potential, which is of great significance for the preventive conservation of sandstone grottoes.