Quantitative analysis and subsequent effects of partitioning of a mono- and dihydric C 4 alcohols into the micelles of cationic surfactants

Abstract

Surfactant–alcohol systems are not uncommon in colloidal chemistry, what is rare is a specific emphasis on the environmental sensitive behaviour of 1-butanol (C 4OH) in different surfactant solutions. Intermediate solubility of C 4OH (in between totally soluble short chain alcohol and partially miscible long chain alcohol) has prompted us to study its partitioning between bulk and micellar phase for monomeric and dimeric surfactants and consequences on micellar parameters. Micellar aggregation number ( N agg) and micelle size has been evaluated by using SANS. Partitioning of C 4OH between bulk and micellar phase was evaluated from 2D NMR NOESY and DOSY experiments. The effect of the structure of C 4 alcohol was evaluated by taking all the above studies for 1,4-butanediol (1,4-BTD), a non-partitioning alcohol by virtue of its terminal hydroxyl groups. Finally, results from SANS and NMR are supported by the routine study of micellar behaviour from conductivity and viscosity. It is revealed that C 4 alcohol plays substantial role in micellization and the two alcohols contribute differently in controlling the overall micellization and micellar parameters.