Abstract

The Volatile Organic Compounds (VOCs) in asphalt fume is widely concerned currently due to its biological toxicity, while the negative effects by asphalt Gaseous Inorganic Compounds (GICs) have not been well quantified and addressed yet. The study investigated the thermodynamic characteristics of base and modified asphalt binders during the multiple phases of releasing the GICs, then the releasing amounts and concentrations of GICs were quantified by fume analyzer. Meanwhile, the environmental impacts of GICs from 4 kinds of asphalt binders have been quantified and interpreted. The results showed that the modified asphalt released less proportion of GICs than base asphalt as heated by same thermal condition according to the TG-DTG and enthalpy analysis. Considering 1 g of asphalt sample, the base asphalt could release extra 8 mg of GICs than modified asphalt, additionally, the emissions of NO2, NO, CO2, and SO2 are all less than the mass of 1 mg. For the environmental effects, the releasing GICs had the greatest impacts on human toxicity due to the intensive CO emission. These results are expected to provide reference and new insights into the improvement of asphalt fumes mitigation.

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