Abstract
AbstractVarious MLM‐type (M, medium‐chain fatty acids; L, long‐chain fatty acids) structured triacylglycerols were produced in pilot‐ or small‐scale packed‐bed reactors by lipasecatalyzed acidolysis. The incorporation and acyl migration of octanoic acid were measured by gas chromatography and Grignard degradation, and ranged from 39.0 to 48.7% and 0.6 to 9.3%, respectively. Quantitation of triacylglycerol molecular species was performed by ammonia negative ion chemical ionization (NICI) mass spectrometry (MS). The proportion of ACN (acyl carbon number) 34 species that contained one C18 fatty acid and two C8∶0′ in samples analyzed, varied from 12.5 to 23.2%. The selected regioisomers MLM and MML within the ACN 34 species group were quantified by NICI tandem MS (MS/MS) and were in the range of 97.1 to 98.4% and 1.6 to 2.9%, respectively. There was no correlation between the level of acyl migration during lipase‐catalyzed esterification and the level of regioisomers of the selected MLM‐type triacylglycerols in the structured lipid samples.
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