Abstract

Abstract Oxygen consumption rates were measured on natural rubber compounds with varying levels of a standard antioxidant package. The oxygen consumption rate measurements were performed at temperatures between 20 °C and 80 °C. The results elucidated the mechanism of antioxidants, including their pro-oxidant effects. The pro-oxidant effect dwindled with time. Integrated oxygen uptake results were calculated from repetitive oxygen consumption rate measurements. Integrated oxygen uptake time temperature master curves with empirical shift factors were combined with elongation-tobreak data to monitor the extent of aging. The stability of the compounds at service life temperatures could be quantified by combining the integrated oxygen uptake shift factors with the tensile elongation-to-break data; thereby to produce an elongation-to-break master curve at service life temperatures.

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