Quantification of lithium deposition under mechano-electrochemical coupling effect

Abstract

The non-uniform growth of lithium dendrites is the main factor causing internal short-circuits and thermal runaway in lithium-ion batteries. Due to the internal environment of the battery being a complex multi-field coupling, the mechanisms of triggering lithium deposition are still unclear. Here, a cross-sectional in-situ optical microscope device was fabricated to observe lithium dendrite evolution. The amount of irreversible and reversible lithium was quantified by the image binarization method and titration gas chromatography, which is used to analyze the relationship between separator deformation, current density, and lithium deposition. The greater the separator deformation and current density, the more irreversible lithium increases. The pore defect mapping algorithm was developed to reconstruct a high-precision three-dimensional finite element model of the separator, which was used to quantify the relationship between displacement loading and the microstructure evolution. A three-dimensional lithium deposition model was established on the actual microstructural parameters of the separator, predicting the concentration and electrochemical field of lithium deposition processes. A phase diagram of lithium precipitated failure in lithium-ion batteries with mechano-electrochemical coupling was developed with silicon-graphite electrode. This work will provide a new direction for understanding the mechanism of lithium deposition and guidance for commercial battery design.