Quantal-classical correspondence impulse theory

Abstract

The quantal impulse cross section is derived in a novel form appropriate for direct classical correspondence. The classical impulse cross section is then uniquely defined and yields the first general classical expression for nl-n(')l(') collisional transitions. The derived cross sections satisfy the optical theorem and detailed balance. Direct connection with the classical binary encounter approximation is also firmly established. The unified method introduced is general in its application to various collision and recombination processes and enables new directions of enquiry to be pursued quite succinctly.