Abstract
Tributyl phosphate-functionalized ionic liquids (TBPs-ILs) have excellent separation performance for actinides and are expected to be used in spent fuel reprocessing. In this study, the radiolytic products of the TBPs-ILs were studied by nuclear magnetic resonance (NMR), high-resolution electrospray ionization mass spectrometry (ESI-MS) and theoretical calculations. The results showed that the substitution reaction mainly occurred on the alkyl chains of phosphate groups, and the main radiolytic products were identified as TBPs-ILs-CF3. Finally, the radiolysis mechanism of TBPs-ILs under gamma irradiation was also proposed.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Radiation physics and chemistry (Oxford, England : 1993)
Paper Title
Journal
Date
