Abstract
With 111In incorporated as a probe into anhydrous powders of InCl, InCl2, and InCl3, time-differential perturbed angular correlation measurements were performed on the 173–247 keV γ–γ cascade in 111Cd. From Fourier analysis of the data information on static electric quadrupole interactions was obtained comprising interaction frequencies, electric field gradient components, and asymmetry parameters. For the trichloride at room temperature the angular correlation is heavily damped and structureless; at T=203 °C InCl3 reveals two static interactions with frequencies ν(1)q =38.8±0.7 MHz and ν(2)q =95.7±2.0 MHz. For InCl2 a single interaction is detected at room temperature, with νq =135.0±1.1 MHz. The α and β phases of InCl are readily distinguished; for the former νq =284.1±2.6 MHz while for the latter at T=167 °C the angular correlation is unperturbed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
