Pyrylium salt-photosensitised degradation of phenolic contaminants present in olive oil wastewaters with solar light: Part II. Benzoic acid derivatives

Abstract

Solar light photodegradation, catalysed by a pyrylium salt, of seven benzoic acids present in olive oil mill, has been studied. Significant percentages of photodegradation (20–40%) have been achieved after 6h of solar exposure for six of the acids, even though they were expected to be difficult to oxidise, due to the presence of an electron-withdrawing carboxylic acid group directly attached to the aromatic ring. Quenching constants for the electron-transfer process between the substrate and the excited catalyst were calculated by means of fluorescence measurements for syringic acid (66×109M−1s−1), gallic acid (51×109M−1s−1), veratric acid (51×109M−1s−1), vanillic acid (48×109M−1s−1), protocatechuic acid (37×109M−1s−1) and p-hydroxybenzoic acid (15×109M−1s−1); no quenching was found for benzoic acid. These photophysical measurements are in good correlation with the yields obtained in the pyrylium salt photocatalysed degradation of those phenolic acids.