Pyrometallurgical processing of high-titaniferous ores.

Abstract

The future development of Ural mineral and raw materials base of steel industry is considerably stipulated by the development of deposits of titanium-magnetite ores, the reserves of which are accounted for near 77% of iron ores of Urals. It was shown, that the content of titanium dioxide as well as harmful impurities in the titanium-magnetite have the decisive meaning for selection of processing technology of them for extraction out of them vanadium and other useful components. Technological schemes of the titanium-magnetite enrichment and industrial methods of titanium-magnetite concentrates processing considered. Examples of titanium-magnetite processing by coke-BF and coke-less schemes given. The problems of blast furnace melting of titanium-magnetite ores highlighted. Main problems relate to formation of refractory compounds in a form of carbo-nitrides during reduction of titanium and infusible masses in blast furnace hearth. It was shown, that intensification if carbides precipitation is stipulated by increase of intensity of titanium reduction at increased temperatures of a heat products and requires the BF heat to be run at minimal acceptable temperature mode. Technological solutions, necessary to implement in blast furnace for iron ore raw materials with increased content of titanium processing were presented, including increase of basicity of slag from 1.2 to 1.25-1.30, increase of pressure at the blast furnace top from 1.8 to 2.2 atm, decrease of silicon content in hot metal from 0.1 to 0.05%, application of manganese-containing additives. It was noted, that theoretically the blast furnace melting of titanium-magnetite is possible at titanium dioxide content in slag up to 40% when application of the abovementioned technological solutions, silicon content in hot metal to 0.01% and very stable heat conditions of a blast furnace. The actuality of titanium and its pigmental dioxide production increase was noted. Possibilities of development of Medvedevskoje and Kopanskoje deposits of high-titaniferous ores in Chelyabinsk region with extraction not only iron and vanadium but also titanium considered.