Pyrolysis of various phytoremediation residues for biochars: Chemical forms and environmental risk of Cd in biochar

Abstract

Various phytoremediation residues (PMRs), including Brassica napus L. (BN), Pennisetum sinese (PS) and Lolium perenne L.(LP), were pyrolyzed at 400, 500, 600 and 700 °C, respectively. A series of sequential and single extractions were employed to analyze the chemical speciation and potential environmental risk of Cadmium (Cd) in different phytoremediation residues-derived biochars (PMBs). The results showed that the exchangeable Cd fraction decreased but the residual Cd fraction increased, indicating the inhibition of bioavailability of Cd and low potential ecological risk index of PMBs. When the temperature was over 600 °C, the Cd in biochar was acceptable to the environment and the leaching concentration of Cd extracted by the three extraction methods (distilled water, SPLP and TCLP) were all under the standard limit. Findings from this study illustrated that the treatment of pyrolysis was feasible for the three kinds of PMRs at 600 °C with acceptable environment risk.