Pyrolysis of Pine Wood in the Presence of Boron-Nitrogen Compounds.

Abstract

The actuality of this research is determined by the intensification of new ways of processing woody biomass. This requires revealing the impact of various physicochemical factors on the thermal degradation of wood biopolymers. Boron-nitrogen surface modifiers are used for wood antisepsis and we decided to check their effect on flammability. The aim of the research was to evaluate the flame retardant effect of boron-nitrogen surface modifiers of wood in an inert atmosphere (nitrogen was used). The evaluation was carried out by thermal analysis of modified and the control pine wood samples. The thermal analysis included thermogravimetry, differential scanning calorimetry and kinetic parameters of thermal degradation. It was found that the flame retardant effect of boron-nitrogen wood surface modifiers was not significantly pronounced in the nitrogen atmosphere. The mechanism of the flame retardant effect of boron-nitrogen compounds is reduced to "shielding" of the surface and increasing the proportion of carbonized residue. On the basis of correlation-regression analysis of kinetic parameters of wood thermodestruction in a nitrogen atmosphere, mathematical models of activation energy dependence on conversion were obtained and substantiated. The developed models can be further applied to calculate the predicted value of wood activation energy in the nitrogen atmosphere at any conversion value.