Pyrite Characteristics and Its Environmental Significance in Marine Shale: A Case Study from the Upper Ordovician Wufeng–Lower Silurian Longmaxi Formation in the Southeast Sichuan Basin, SW China

Abstract

Pyrite, as a characteristic mineral in organic-rich marine shale, is a significant index for the interpretation of paleoredox conditions. In this study, based on drilling cores and focused ion beam-scanning electron microscopy (FIB-SEM), the occurrence, diameter and particle size distribution of pyrites from 32 samples obtained from the Wufeng–Longmaxi Formation in the southeast Sichuan Basin were analyzed. The results show that pyrite displays various occurrences at the macro-scale and micro-scale. At the macro-scale (mm–cm), pyrite laminations, nodular pyrites and lenticular pyrites can be found from drilling cores. At the micro-scale (nm–µm), the common occurrences of pyrite are pyrite framboids, euhedral pyrites and infilled pyrite framboids. According to the formation mechanism of pyrites, pyrites can be divided into syngenetic pyrites and diagenetic pyrites. The infilled pyrite framboids are categorized as diagenetic pyrites. The mean pyrite framboid diameters (Mean, D) range from 2.94 µm to 5.33 µm (average of 4.26 µm), with most samples showing pyrite framboid diameters from 3.5 μm to 4.8 μm. Most of the diameters of the framboid microcrystals (Mean, d) are less than 0.4 µm. Therefore, according to the (Mean, D) and the (Mean, d), the pyrite framboids can be divided into three sizes: syngenetic framboids (SF, D < 4.8 µm, d ≤ 0.4 µm), early diagenetic framboids (EDF, D > 4.8 µm, d > 0.4 µm) and late diagenetic framboids (LDF, D < 4.8 µm, d > 0.4 µm). Additionally, box-and-whisker charts of the diameter, standard deviation/skewness value of the mean diameter of pyrite framboids (Mean, D) and the ratio of trace elements indicate that the sedimentary water body was a euxinic–dysoxic environment. Euxinic conditions dominated the Wufeng Formation to the lower part of the Long11-3 section, which is beneficial for the preservation of organic matter. However, the middle-upper part of the Long13-Long12 sub-member is a dysoxic sedimentary environment.