Pyridyldicarboxamide-based multinuclear complexes: Syntheses, structural characterizations, and magnetic properties

Abstract

Using the pyridine dicarboxamide derivative N,N′-bis(1,3,4-thiadiazol-2-yl)-2,6-pyridinedi-carboxamide (H 2-btapca) as ligand, two novel polynuclear complexes: dimeric {[Cu 2( μ 2-O 2H)(btapca) 2]·DMF·H 2O} ( 1) and tetrameric {[Ni 4(( μ 2-O 2H) 2(btapca) 4)]·DMF·MeOH·3.5H 2O} ( 2) were obtained. In complex 1, two center Cu(II) ions are bounded by two btapca ligands and one aqueous molecule acting as a μ 2-H 2O bridge connect them together. Complex 2 is a tetrameric complex, in which the based backbone is an assumed Ni 4 tetrahedron with two μ 2-O 2H bridges existing inside the tetrahedron forming a basic [Ni 2( μ 2-O 2H)] 2 core, which are surrounded by four btapca ligands. The magnetic properties of the two polynuclear complexes were determined, the results show that for both of the two complexes, the overall weak ferromagnetic exchange interactions between central metal ions are evident, the best fitting parameters are: J = 7.47 cm −1 ( g = 2.21) for dimeric Cu(II) complex 1, and 2 J 1 = 4.8 cm −1, 2 J 2 = −0.00204 cm −1( g = 2.14, zJ′ = 0.00077 cm −1) for tetrameric Ni(II) complex 2.