Abstract
One novel 1D polymer, [Cd2(m-BrPhHIDC)2(4,4′-bipy)(H2O)2]n (1) (m-BrPhH3IDC = 2-(3-bromophenyl)-1H-imidazole-4,5-dicarboxylic acid; 4,4′-bipy = 4,4′-bipyridine), has been hydrothermally synthesised and characterised by single-crystal X-ray diffraction, elemental analysis, IR, powder X-ray diffraction (PXRD) and thermogravimetric analysis. Polymer 1 composed of tetranuclear square [Cd2(m-BrPhHIDC)2] second building units and 4,4′-bipy bridges shows the interesting tunable luminescence properties aroused by pyridine. A luminescence enhance mechanism has been proposed.
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