Abstract

In the treatment of pyrazolo(1,5-a]pyridines with dimethylformamide and,phosphorus oxychloride, Vilsmeier-Haack formylation proceeded at the 3-position, giving 3-pyrazolo[1,5-a]pyridinecarboxaldehydes. Reaction of the pyrazolo[1,5-a]pyridine with acyl halide gave 3-acylpyrazolo[1,5-a]pyridines. Conversion of the formyl group into the alkenyl group was achieved easily by Wittig reaction

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