Abstract

AbstractSince the mid-80s, new classes of superconductors have been discovered in which the origin of superconductivity cannot be attributed to the electron–ion interactions at the heart of conventional superconductivity. Most of these unconventional superconductors are strongly correlated electron systems, and identifying (or even more difficult, predicting) the precise superconducting state has been, and sometimes remains, an actual challenge. However, in most cases, it has been demonstrated that in these materials the spin state of the Cooper pairs is a singlet state, often associated with a ‘d-wave’ or ‘$$s +/-$$ s + / - ’ orbital state. For a few systems, a spin-triplet state is strongly suspected, like in superfluid $$^3$$ 3 He; this leads to a much more complex superconducting order parameter. This was long supposed to be the case for the d-electron system Sr$$_2$$ 2 RuO$$_4$$ 4 , and is very likely realized in some uranium-based (f-electron) ‘heavy fermions’ like UPt$$_3$$ 3 (with multiple superconducting phases) or UGe$$_2$$ 2 (with coexisting ferromagnetic order). Beyond the interest for these materials, p-wave superconductivity is presently quite fashionable for its topological properties and the prediction that it could host Majorana-like low energy excitations, seen as a route towards robust (topologically protected) qubits. The aim of these notes is to make students and experimentalists more familiar with the d-vector representation used to describe p-wave (spin triplet) superconductivity. The interest of this formalism will be illustrated on some systems where p-wave superconductivity is the prime suspect.

Highlights

  • The purpose of these notes is only to cover some aspects of spin-triplet superconductors, not so commonly covered in the excellent textbooks available on superconductivity, in general, and unconventional superconductors, in particular

  • = −ψ αβ dk e−ik.r β|(k ∧ ∇)D(k)|α |αβ, so − i n .L| = | (−in ·Lkd(k)), with Lk = k ∧ 1 ∇k . i. This last expression shows that a rotation in real space acts, as it should, on the order parameter according to its orbital state: p-wave, f -wave, ... for a triplet superconductor, transposed as usual in the reciprocal space

  • We can understand that any state | = 0| ↑↓ + ↓↑ can be considered as an ‘equal spin pairing’ (ESP) state, with equal weight on | ↑↑ and | ↓↓ spin components

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Summary

Introduction

The purpose of these notes is only to cover some aspects of spin-triplet superconductors, not so commonly covered in the excellent textbooks available on superconductivity, in general, and unconventional superconductors, in particular. Let us choose to quote only two: the seminal Reviews of Modern Physics paper “A theoretical description of the new phases of liquid 3He” by A. J. Leggett [1], which gives both very advanced and detailed insights on the theory of the pwave order parameter of superfluid 3He, and pedagogical and enlightening treatment of the microscopic Bardeen–Cooper–Schrieffer (BCS) theory of anisotropic superconductors and the other, which covers the very important symmetry aspects of unconventional superconductors in crystalline materials, is the book ‘Introduction to unconventional superconductivity’ by V. We concentrate on some basic aspects of the description of spintriplet superconductors, which are often bewildering, at least to experimentalists

Odd-Parity Pairing
Position of the Problem
Useful Formula for Pauli Matrices
Rotation of a 3D Vector
Rotation in Spin Space
Rotation in Real Space
Change of Quantization Axis
Amplitude of the d-Vector
Spin Direction
Non-unitary States
Orbital Moment
Excitation Energy of Quasiparticles
The Spin–Orbit Issue
Spin–Orbit and the Superconducting Order Parameter
Anisotropy of the Susceptibility for the Strong Spin–Orbit Case
Phases of Superfluid 3He
B-Phase
A-Phase The A-phase of superfluid 3He is simply characterized by d(k) = 3 (ky + ikz, 0, 0) , 2
A1 Phase
Planar and Polar Phases
UPt3 and Sr2RuO4
Phases of UPt3
E2u Representation
E1u Representation
Ferromagnetic Superconductors
ESP States
Symmetries
Microscopic Model
6.11.1 Proof of the Cayley–Klein Relation
6.11.5 Equivalence of ESP Unitary States and Pure |Sz = 0 States

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