Abstract

Degradation of backsheets (BSs) and encapsulant polymer components of silicon PV modules is recognized as one of the main reasons for losses in PV plant performance and lifetime expectations. Here, we report initial insights into the correlation between BS composition of PV-modules and PV power station performance by using a combination of lab- and field-imaging, as well as spectroscopic and electrical characterizations. Using field-suitable near-infrared absorption (NIRA) spectroscopy, the BS structure of 518 PV-modules, 2.5 % of the PV-modules in a 5 MWp PV power station, was identified on-site. The variance of the BS composition was found to be heterogeneous across PV-modules of the same power class from the same manufacturer. Polyamide-based BSs cause in 10 out of 100 inverters ground impedance values below 400 kΩ, which is a typical threshold for inverters connecting to the grid. For fluorinated coating-based BSs this low value is reached 20 times. We conclude these numbers best as possible from the available monitoring data of inverters associated with BS-types from NIRA. The identification of degraded coating-based BSs is challenging, since visually they look healthy and undistinguishable to well performing BSs. The present results demonstrate that a deeper understanding of the relationship between bill-of-materials and performance of PV-modules is necessary to avoid/minimize inverter shut-downs, and that it can be achieved by using combinations of selected field and lab characterization methods with monitoring data. • Analyzing backsheets of 518 PV-modules in the field using near-infrared spectroscopy. • Distinguishing various backsheet types: polyamide, PVF-PET-PE, PVDF-PET-PE, FC-PET-PP. • Leakage resistance loss rate differs strongly for FC-based and PA-based BSs. • Monitoring data of inverter indicate different loss of ground impedance associated with differing BS material. • Inverter shut-down are observed at least twice as often in inverters with FC-based BS as in those with PA-based BS.

Highlights

  • Polymeric components of silicon PV-modules - transparent encapsulants and air-side backsheets (BSs) perform important functions for safe operation of PV power stations

  • The present results demonstrate that a deeper understanding of the relationship between bill-of-materials and performance of PV-modules is necessary to avoid/minimize inverter shut-downs, and that it can be achieved by using combinations of selected field and lab characterization methods with monitoring data

  • The objective of this study is to investigate the field performance of PV-modules depending on different BS types and their impact on PV power station performance and inverter operability

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Summary

Introduction

Polymeric components of silicon PV-modules - transparent encapsulants and air-side backsheets (BSs) perform important functions for safe operation of PV power stations. They protect the fragile solar cells from mechanical damage and degradation due to corrosion at ambient operating conditions, and they provide electrical insulation from the environment. A loss in chemical stability, mechanical strength, and electrical insulation properties of BSs and encapsulants results in the deterioration of their protective functions [1,2,3,4]. Various changes of the properties of polymer materials, in particular ethylene vinyl acetate (EVA) encapsulant and BSs of different types were detected in field-aged PV-modules and have been discussed in literature throughout the last years. Variations of BS modifications include discoloration (yellowing, browning), delamination, peeling, macroscopic crack structures, burn marks, corrosion, etc [1,2, 4,5,6,7,8,9,10,11]

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