Abstract
A molecular dynamics model is developed to investigate the pure vibrational dephasing of [Formula: see text] in solvent at temperatures ranging from room temperature to 100 K. The triiodide ion is described by a valence bond model which responds to the field of the classical solvent molecules. We find that the pure dephasing rate does not change much with temperature. This result can then be interpreted in terms of of Kubo lineshape theory.
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