Abstract

The far infrated spectrum of dilute solutions of HCl and DCl dissolved in liquid SF 6 at 0°c is observed in the frequency region 30 cm −1. A broad absorption band is obtained for DCl which is in excellent agreement with the band envelope defined by the relative integrated intensity of each of the pure rotational transitions in the gas phase. The HCl spectrum, however, shows clearly resolved lines superimposed on a broad absorption band. These lines are readily identifiable with the pure rotational lines in the gas phase.

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