Abstract
The ground state pure rotational spectrum of silacyclopentane (SCP) has been investigated using both Fourier Transform Microwave (FTMW) and chirped pulse Fourier Transform Microwave (cp-FTMW) spectroscopies. In addition to the parent species, the spectra of the 13C, 29Si and 30Si singly-substituted isotopologues were recorded in the 6–24 GHz region in natural abundance. Structural analysis confirms that the ground state has C 2 symmetry and the geometric parameters determined based on heavy atom substitution include the bond distances, bond angles and dihedral angles of the SCP ring backbone.
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