Pulse-induced mechanoluminescence of ultraviolet-irradiated SrAl2O4:Eu,Dy phosphors

Abstract

The SrAl2O4:Eu,Dy phosphors prepared by solid state reaction technique in a reduced atmosphere of 95% Ar+5% H2 exhibit very intense mechanoluminescence (ML) which can be seen in daylight with naked eye. When the phosphors are deformed by the impact of a low-power electric hammer, initially the ML intensity increases with time, attains a maximum value and then decreases with time. After the threshold pressure, the peak of ML intensity Im and the total ML intensity IT increase with the increasing value of the impact pressure. For the ML excited by the pressure pulse of short duration, two decay times of ML are observed; however, for the ML excited by the pressure pulse of long duration, only one decay time is observed. The ML intensity decreases with successive applications of pressure on SrAl2O4:Eu,Dy phosphors. For the low applied pressure in the range below the limit of elasticity recovery of ML intensity takes place when the sample is exposed to ultraviolet (UV) light. This fact indicates that the vacant traps produced during the application of pressure pulses get filled during the exposure of the sample to UV light. The ML in the elastic region of SrAl2O4:Eu,Dy phosphors can be understood on the basis of the piezoelectrically induced detrapping model. The non-irradiated SrAl2O4:Eu2+,Dy3+ phosphors exhibit ML during the fracture of the compact mass of phosphors whose ML intensity is less when compared to that of the UV-irradiated compact masses. The ML induced by pressure pulses may be useful for determining the magnitude and rise time of unknown pressure pulses and to determine the lifetime of charge carriers in shallow traps.