Abstract
AbstractWe report on the synthesis of hydrogen atoms in different Si8O12R8 cages (R = (CH2)n H with n = 0–3) by both radiation chemistry and ion implantation. The efficiencies of both mechanisms have been studied quantitatively and attempts to optimise the process have been made. Spectral properties and relaxation times were investigated using both cw and pulsed EPR measurements. The Hahn Echo decay behaviour and the dependence of T 1 and T 2 on the side groups R of the cage revealed information about the predominant relaxation mechanisms. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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