Abstract
A theoretical study of the limiting current in pulse polarography is given for first-order regeneration mechanisms: fractional regeneration and catalytic regeneration (regeneration ≥1). Rigorous equations for the current have been derived, taking into account both the expanding plane electrode and the expanding sphere electrode models. In addition, the corresponding asymptotic solutions which show the behavior of the current when the rate constant values are large, have been derived by using the steady-state approximation.
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More From: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
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