Abstract
The method of pulse photolysis has been used to determine termination rate constants of primary peroxy radicals in benzene at 295 K. Radicals CH3O 2 . have been found to decay with the rate constant 2k6=3.7×108 M−1 s−1 and radicals (CH3)3 COOC(CH3)CH2O 2 . with 2k8=1.2×108 M−1 s−1, the rate constant of cross-recombination for both radicals being 2.4×108 M−1 s−1.
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