Pt–RuO2 electrodes prepared by thermal decomposition of polymeric precursors as catalysts for direct methanol fuel cell applications

Abstract

Abstract The electrocatalytic activity of Pt and RuO 2 mixed electrodes of different compositions towards methanol oxidation was investigated. The catalysts were prepared by thermal decomposition of polymeric precursors and characterized by energy dispersive X-ray, scanning electronic microscopy, X-ray diffraction and cyclic voltammetry. This preparation method allowed obtaining uniform films with controlled stoichiometry and high surface area. Cyclic voltammetry experiments in the presence of methanol showed that mixed electrodes decreased the potential peak of methanol oxidation by approximately 100 mV (RHE) when compared to the electrode containing only Pt. In addition, voltammetric experiments indicated that the Pt 0.6 Ru 0.4 O y electrode led to higher oxidation current densities at lower potentials. Chronoamperometry experiments confirmed the contribution of RuO 2 to the catalytic activity as well as the better performance of the Pt 0.6 Ru 0.4 O y electrode composition. Formic acid and CO 2 were identified as being the reaction products formed in the electrolysis performed at 400 and 600 mV. The relative formation of CO 2 was favored in the electrolysis performed at 400 mV (RHE) with the Pt 0.6 Ru 0.4 O y electrode. The presence of RuO 2 in Pt–Ru-based electrodes is important for improving the catalytic activity towards methanol electrooxidation. Moreover, the thermal decomposition of polymeric precursors seems to be a promising route for the production of catalysts applicable to DMFC.