Abstract
A Pt(II) catalyst showed a drastic effect on hydroarylation of alkynes with pyrroles and furans compared with Pd(OAc) 2 catalyst. The hydroarylation reactions proceeded smoothly under mild conditions to give double-hydroarylation products in good yields. Mono-adducts were formed only when the second hydroarylation was inhibited by steric hindrance of substrates or low reactivity of the mono-adducts.
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