Abstract
A kind of highly efficient and low cost supported-Pt catalyst for oxidation of toluene is obtained through controlling both the chemical state of Pt active sites and surface properties of supports. The optimized Pt/Al2O3 catalyst with Pt loading as low as 0.1 wt% could completely convert toluene (1000 ppm) to CO2 at about 180 ℃ under a space velocity of 24,000 mL g−1 h−1. It also exhibits a high stability and moisture resistance properties under reaction atmosphere. TOF value calculated with the dispersion of Pt can reach 0.0685 s-1, representing a high utilization efficiency of Pt. A series of characterizations are carried out to investigate the key factors affecting the catalytic performance of Pt/Al2O3, and disclose the concrete role of Pt and Al2O3 in the activation of molecular oxygen and toluene. In situ DRIFTS and EPR results show that Pt is the active center for O2 activation. Metallic Pt nanoparticles (Pt0) can activate the molecular O2 even at room temperature. Al2O3 offers sites for the adsorption of toluene and desorption of CO2 product. The weak and medium strength of acid-base sites favorite the adsorption and desorption process. The oxidation of toluene over Pt/Al2O3 obeys modified L-H mechanism. The synergistic effect of metallic Pt nanoparticles and suitable Al2O3 support is critical for obtaining highly efficient Pt-based catalysts with low Pt contents for toluene oxidation.
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